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17057

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Probing dynamic library of metal-oxo building blocks with γ-cyclodextrin.

著者 Falaise C , Moussawi MA , Floquet S , Abramov PA , Sokolov MN , Haouas M , Cadot E
J Am Chem Soc.2018 Aug 29 ; ():.
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Formation of one of the most representative polyoxometalate (POM) archetypes, namely the Lindqvist anion MO with M = Mo or W, was considered as elusive in aqueous solution. Herein, we report on the host-guest stabilization of the MO species with M = Mo or W from aqueous solution using γ-cyclodextrin as trapping agent. The adduct {MO@γ-CD} reveals remarkable hydrolytic stability that offers new opportunities for exploring potentialities of molybdates or tungstates in the field of biology and medicine, when combined to CDs as efficient drug carrier/delivery agents.
PMID: 30156413 [PubMed - as supplied by publisher]
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