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Fine Tuning and Specific Binding Sites with a Porous Hydrogen-Bonded Metal-Complex Framework for Gas Selective Separations.

著者 Bao Z , Xie D , Chang G , Wu H , Li L , Zhou W , Wang H , Zhang Z , Xing H , Yang Q , Zaworotko MJ , Ren Q , Chen B
J Am Chem Soc.2018 Mar 14 ; ():.
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Research on HOFs has been developed for quite a long time; however, those with both established permanent porosities and functional properties are extremely rare due to weak hydrogen-bonding interactions among molecular organic linkers which are much more fragile and difficult to stabilize. Herein, through judiciously combining the superiority of both the moderately stable coordination bonds in MOFs and hydrogen bonds, we have realized a microporous hydrogen-bonded organometallic framework HOF-21, which not only shows permanent porosity but also exhibits highly selective separation performance of C2H2/C2H4 at room temperature. The outstanding separation performance can be ascribed to the super-imposed hydrogen-bonding interaction between C2H2 and SiF62- on both ends as validated by both modeling and neutron powder diffraction experiments. More importantly, the collapsed HOF-21 can be self-restored by simply immersing it into water or salt solution. To the best of our knowledge, such extraordinary water stability of HOF-21, meanwhile restorability was observed for the first time in HOFs, underlying the bright perspective of such new special HOF materials for industrial usage.
PMID: 29540058 [PubMed - as supplied by publisher]
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