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A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands.

著者 Schäffer C , Todea AM , Bögge H , Floquet S , Cadot E , Korenev VS , Fedin VP , Gouzerh P , Müller A
Dalton Trans.2012 Nov 12 ; ():.
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Fakultät für Chemie, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany. a.mueller@uni-bielefeld.de.

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Addition of [Mo(2)(V)O(2)(μ-O)(μ-S)(aq)](2+) linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W(5)} units logically in the self-assembly of a mixed oxide/sulphide {W(VI)(72)Mo(V)(60)}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)(2) and (μ-S)(2) scenarios are known) and providing options to influence differently important capsule-substrate interactions.
PMID: 23147405 [PubMed - as supplied by publisher]
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